2-Hydroxyethyl acrylate → epsilon-CAPROLACTONE

HRID 1109089

반응식

HRID 1109089 반응식
[C:1]([O:5][CH2:6][CH2:7]O)(=[O:4])[CH:2]=[CH2:3].[C:9](OC[CH2:16][OH:17])(=O)C(C)=C.C(OC[CH:24]([OH:26])C)(=O)C=C.C(OC[CH:34]([OH:36])C)(=O)C(C)=C.[C:37](OCCCO)(=[O:40])C=C.[C:46](OCCCO)(=[O:50])C(C)=C.C(OCC(O)CC)(=[O:59])C=C.C(OCC(O)CC)(=O)C(C)=C.C(OCCC(O)C)(=O)C=C.C(OCCC(O)C)(=O)C(C)=C.C(OCCCCO)(=O)C=C.C(OCCCCO)(=O)C(C)=C>>[OH:40][CH2:37][C:7]([CH2:16][OH:17])([CH2:6][O:5][CH2:1][C:2]([CH2:3][OH:59])([CH2:24][OH:26])[CH2:34][OH:36])[CH2:46][OH:50].[C:1]1(=[O:4])[O:5][CH2:6][CH2:7][CH2:9][CH2:3][CH2:2]1

참가 물질

14

반응물 12

HCID 131652-Hydroxyethyl acrylateHCID 133602-Hydroxyethyl MethacrylateHCID 135392-Hydroxypropyl methacrylateHCID 176943-Hydroxypropyl methacrylateHCID 331012-Propenoic acid, 3-hydroxypropyl esterHCID 612492-Hydroxypropyl acrylateHCID 704574-Hydroxybutyl methacrylateHCID 755884-Hydroxybutyl acrylateHCID 1028112-Propenoic acid, 2-hydroxybutyl esterHCID 30179872-Propenoic acid, 2-methyl-, 3-hydroxybutyl esterHCID 43466562-Hydroxybutyl methacrylateHCID 139321793-Hydroxybutyl acrylate

생성물 2

HCID 10401epsilon-CAPROLACTONEHCID 31352Dipentaerythritol

실험 절차

The compound (A) can also be prepared by polymerization of the reaction product of the compound [5] with an α,β-unsaturated hydroxyl compound, such as 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 3-hydroxypropyl acrylate, 3-hydroxypropyl methacrylate, 2-hydroxybutyl acrylate, 2-hydroxybutyl methacrylate, 3-hydroxybutyl acrylate, 3-hydroxybutyl methacrylate, 4-hydroxybutyl acrylate, 4-hydroxybutyl methacrylate, dipentaerythritol hexa(meth)acrylate, hexa(meth)acrylate of a compound formed by addition of dipentaerythritol with ε-caprolactone and the like, or with a corresponding α,β-unsaturated thiol compound. The compound (A) can also be prepared by copolymerization of the reaction product with an α,β-unsaturated compound having no functional groups. Examples of the α,β-unsaturated compound having no functional groups are: methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, isobutyl (meth)acrylate, sec-butyl (meth)acrylate, t-butyl (meth)acrylate, cyclohexyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, lauryl (meth)acrylate, stearyl (meth)acrylate, styrene, α-methylstyrene, p-vinyltoluene, acrylonitrile and the like.

출처 및 근거

ORD 기록
ord-7c9616d1695443a9a521cbd906a16741
출처 데이터셋
uspto-grants-1994_06
특허 번호
US05319024

연결된 노트

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