Isobutyl acrylate → Mercaptopropionic acid isobutyl ester
반응식
C(=S)([S-])[S-:2].[Na+].[Na+].[C:7]([O:11][CH2:12][CH:13]([CH3:15])[CH3:14])(=[O:10])[CH:8]=[CH2:9]>Cl>[CH2:12]([O:11][C:7](=[O:10])[CH:8]([SH:2])[CH3:9])[CH:13]([CH3:15])[CH3:14]참가 물질
4
반응 조건
- 온도
- -10 °C
실험 절차
There were present in a stirring apparatus 577.5 grams of a 40% sodium trithiocarbonate solution (corresponding to 1.5 moles). Under stirring at -10° C. there were dropped in 128 grams of isobutyl acrylate (1.0 mole). Post stirring was continued for a further 10 minutes and then the mixture was acidified with 350 ml of 32% hydrochloric acid. After the phase separation the organic phase was fractionally distilled. There were obtained 128 grams of mercaptopropionic acid isobutyl ester (corresponding to a yield of 79%).
후처리
- stirringPost stirring
- customAfter the phase separation the organic phase
- distillationwas fractionally distilled
출처 및 근거
- ORD 기록
- ord-b6771bab4bc64356b1c6a5c96657ebee
- 출처 데이터셋
- uspto-grants-1984_12
- 특허 번호
- US04490307
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