Azobisisobutyronitrile → HCID 20513501, 화합물

HRID 1164057

반응식

HRID 1164057 반응식
[CH3:1][O:2][C:3]1[C:8]([CH3:9])=[CH:7][CH:6]=[CH:5][C:4]=1[O:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1.[Br:17]N1C(=O)CCC1=O.N(C(C)(C)C#N)=NC(C)(C)C#N>C1C=CC=CC=1>[CH3:1][O:2][C:3]1[C:8]([CH2:9][Br:17])=[CH:7][CH:6]=[CH:5][C:4]=1[O:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1

참가 물질

5

반응물 3

HCID 6547AzobisisobutyronitrileHCID 67184N-bromobutanimideHCID 20082997Phenyl 2-methoxy-3-methylphenyl ether

생성물 1

HCID 20513501HCID 20513501, 화합물수율 103.5%

시약·촉매·용매 1

HCID 241Benzene용매

실험 절차

A mixture of phenyl 2-methoxy-3-methylphenyl ether (6 g), N-bromosuccinimide (5.2 g) and azobisisobutyronitrile (500 mg) in dried benzene (60 ml) was treated in a similar manner to that of Example 14-(3) to give oily phenyl 2-methoxy-3-bromomethylphenyl ether (8.5 g).

후처리

  1. additionwas treated in a similar manner to that of Example 14-(3)

출처 및 근거

ORD 기록
ord-9585e5e9803040eeb09a1d3008e26a77
출처 데이터셋
uspto-grants-1983_01
특허 번호
US04367238

연결된 노트

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