Vinyltrichlorosilane → HCID 13463725, 화합물

HRID 1172049

반응식

HRID 1172049 반응식
[CH:1]([Si:3]([Cl:6])([Cl:5])[Cl:4])=[CH2:2].[Cl:7][Si:8]([Cl:15])([Cl:14])[CH2:9][CH2:10][SiH:11]([Cl:13])[Cl:12]>>[Cl:4][Si:3]([Cl:6])([Cl:5])[CH2:1][CH2:2][Si:11]([Cl:13])([Cl:12])[CH2:10][CH2:9][Si:8]([Cl:15])([Cl:14])[Cl:7]

참가 물질

3

반응물 2

HCID 6413VinyltrichlorosilaneHCID 1019294941,1,1,4,4-Pentachloro-1,4-disilabutane

생성물 1

HCID 13463725HCID 13463725, 화합물

실험 절차

Vinyltrichlorosilane (16.8 g, 104 mmol) was heated to 60° C. and 100 μL 10% H2PtCl6/IPA-solution was added. 1,1,1,4,4-pentachloro-1,4-disilabutane (20.4 g, 77.7 mmol) was added slowly during 20 min so that the temperature did not exceed 100° C. The reaction was allowed to proceed for 12 hours at 100° C., after which it was distilled under vacuum at 115-130° C./<1 mbar. The yield was 31.5 g (74.3 mmol, 96%).

후처리

  1. customdid not exceed 100° C
  2. distillationafter which it was distilled under vacuum at 115-130° C./<1 mbar

출처 및 근거

ORD 기록
ord-ecc149b50f6746d4a9fec7163b23f264
출처 데이터셋
uspto-grants-2010_11
특허 번호
US07833820B2

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