Hydroxyamine hydrochloride → HCID 136364583, 화합물

HRID 1200033노트

반응식

HRID 1200033 반응식
[Na].[C:2]([C:5]1[CH:6]=[CH:7][C:8]([C:11]#[N:12])=[N:9][CH:10]=1)([OH:4])=[O:3].Cl.[NH2:14][OH:15]>C(O)C>[C:2]([C:5]1[CH:6]=[CH:7][C:8]([C:11](=[N:14][OH:15])[NH2:12])=[N:9][CH:10]=1)([OH:4])=[O:3]

참가 물질

5

반응물 3

HCID 443297Hydroxyamine hydrochlorideHCID 27611086-Cyanopyridine-3-carboxylic acidHCID 5360545Sodium2회

생성물 1

HCID 136364583HCID 136364583, 화합물

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

Sodium (18 mmol) is added to a flask containing 20 ml of ethanol. After the sodium has dissolved, 3.8 mmol of 5-carboxy-2-cyanopyridine and 18 mmol of hydroxylamine hydrochloride are added, and the solution is refluxed for 5 h. After cooling, the resulting precipitate is filtered off and recrystallized from water; m.p.>300°.

후처리

  1. temperaturethe solution is refluxed for 5 h
  2. temperatureAfter cooling
  3. filtrationthe resulting precipitate is filtered off
  4. customrecrystallized from water

출처 및 근거

ORD 기록
ord-431e14a2a21948e6bbabb6164684945e
출처 데이터셋
uspto-grants-1990_02
특허 번호
US04904675

반응 노트

불러오는 중…