Potassium Carbonate → HCID 178527862, 화합물

HRID 1244271

반응식

HRID 1244271 반응식
CN(C)/[CH:3]=[CH:4]/[C:5]([C:7]1[CH:12]=[CH:11][C:10]([Cl:13])=[CH:9][CH:8]=1)=O.[NH2:15][C:16]([NH2:18])=[S:17].C(=O)([O-])[O-].[K+].[K+]>C(O)C>[Cl:13][C:10]1[CH:11]=[CH:12][C:7]([C:5]2[CH:4]=[CH:3][N:18]=[C:16]([SH:17])[N:15]=2)=[CH:8][CH:9]=1

참가 물질

5

반응물 3

HCID 11430Potassium CarbonateHCID 2723790ThioureaHCID 5375260(E)-1-(4-chlorophenyl)-3-(dimethylamino)prop-2-en-1-one

생성물 1

HCID 178527862HCID 178527862, 화합물

시약·촉매·용매 1

HCID 702Ethanol용매

반응 조건

온도
85 °C

실험 절차

To a solution of (2E)-3-(dimethylamino)-1-(4-chlorophenyl)prop-2-en-1-one (1.5 g, 7.2 mmol) in ethanol (25 ml) was added thiourea (0.60 g, 7.9 mmol) and potassium carbonate (K2CO3) (1.19 g. 8.63 mmol). The resulting suspension was heated to 85° C. for 12 hours then cooled to ambient temperature. The resulting solid was collected and thoroughly washed with water and hexanes to provide a beige solid: EI-MS (m/z) 222 [M+1]+.

후처리

  1. temperaturethen cooled to ambient temperature
  2. customThe resulting solid was collected
  3. washthoroughly washed with water and hexanes
  4. customto provide a beige solid

출처 및 근거

ORD 기록
ord-7466dac3b45341168ec0e634a3e6fcb6
출처 데이터셋
uspto-grants-2006_10
특허 번호
US07122544B2

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