Acetyl chloride → Acetyltriphenylene

HRID 1253381

반응식

HRID 1253381 반응식
[CH:1]1[C:18]2[C:17]3[C:12](=[CH:13][CH:14]=[CH:15][CH:16]=3)[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.[Al+3].[Cl-].[Cl-].[Cl-].[CH3:23][C:24](Cl)=[O:25]>C(Cl)Cl>[C:24]([C:4]1[C:5]2[C:6]3[C:11](=[CH:10][CH:9]=[CH:8][CH:7]=3)[C:12]3[C:17](=[CH:16][CH:15]=[CH:14][CH:13]=3)[C:18]=2[CH:1]=[CH:2][CH:3]=1)(=[O:25])[CH3:23]

참가 물질

5

반응물 3

HCID 6367Acetyl chlorideHCID 9170TriphenyleneHCID 6451240Aluminum(III) Chloride

생성물 1

HCID 86641842Acetyltriphenylene수율 97%

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

Triphenylene (1 equivalent) is reacted at 0° C. with 2.1 equivalents of AlCl3 and 21.0 equivalents of CH3COCl in CH2Cl2. After stirring at room temp. for 3 hours, the reaction product (acetyltriphenylene) was obtained in 97% yield, and is used in step b).

출처 및 근거

ORD 기록
ord-50762937bfe84de5b8de680d0acea52e
출처 데이터셋
uspto-grants-2013_06
특허 번호
US08455112B2

연결된 노트

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