Chloroacetic Acid → Dihexyl ether

HRID 1270006

반응식

HRID 1270006 반응식
[OH-].[Na+].Cl[CH2:4][C:5]([OH:7])=O.[CH2:8](Cl)[CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].[N+]([O-])(O)=O.[C:19](O)(=O)[CH3:20].[CH2:23](O)[CH3:24]>O>[CH2:8]([O:7][CH2:5][CH2:4][CH2:23][CH2:24][CH2:19][CH3:20])[CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

참가 물질

7

반응물 5

HCID 300Chloroacetic AcidHCID 702EthanolHCID 109921-ChlorohexaneHCID 14798Sodium HydroxideHCID 86584207Acetic acid nitric acid

생성물 1

HCID 8198Dihexyl ether

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
95 °C

실험 절차

Cellulose (20 g), sodium hydroxide (10 g), water (30 g), and ethanol (150 g) are charged into a 500 ml glass reactor. The resulting alkali cellulose is stirred 45 minutes at 25° C. Then monochloroacetic acid (15 g) and hexylchoride (1 g) are added and the temperature raised over time to 95° C. and held at 95° C. for 150 minutes. The reaction is cooled to 70° C., and then cooled to 25° C. Neutralization is accomplished by the addition of a sufficient amount of nitric acid/acetic acid to achieve a slurry pH of between 8 and 9. The slurry is filtered to obtain a hexylether of CMC.

후처리

  1. temperatureThe reaction is cooled to 70° C.
  2. temperaturecooled to 25° C
  3. filtrationThe slurry is filtered

출처 및 근거

ORD 기록
ord-2a7ae9fe8e1d4ed8acdbe10a453a91be
출처 데이터셋
uspto-grants-2007_04
특허 번호
USRE039557E1

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