O-Xylene → 1,14-Bis(triethoxysilyl)tetradecane

HRID 1350541

반응식

HRID 1350541 반응식
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH:13]=[CH2:14].[CH2:15]([O:17][SiH:18]([O:22][CH2:23][CH3:24])[O:19][CH2:20][CH3:21])[CH3:16].C([Si](C)(C)[O:28][SiH3:29])=C.[C:32]1([CH3:39])C(C)=CC=CC=1>>[CH2:15]([O:17][Si:18]([O:22][CH2:23][CH3:24])([O:19][CH2:20][CH3:21])[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH2:1][Si:29]([O:28][CH2:32][CH3:39])([O:19][CH2:20][CH3:21])[O:17][CH2:15][CH3:16])[CH3:16]

참가 물질

5

반응물 4

HCID 7237O-XyleneHCID 13830TriethoxysilaneHCID 30875Tetradeca-1,13-dieneHCID 123658807Vinyl dimethyldisiloxane

생성물 1

HCID 225598111,14-Bis(triethoxysilyl)tetradecane

실험 절차

The synthesis method is described in detail by, e.g., H. W. Oviatt et al., Chem. Mater., 1993, 5, 943, and 1,14-bis(triethoxysilyl)tetradecane was synthesized following the above method. A mixture of 25 g of 1,13-tetradecadiene (Aldrich), 44.4 g of triethoxysilane (Shin-etsu Silicones) and 0.1 mL of a 3% xylene solution of platinum complex of bis((vinyl dimethyldisiloxane) (Shin-etsu Silicones) was prepared and stirred at room temperature in a nitrogen atmosphere for 3 days. The reaction effluent was purified by distillation, to obtain 1,14-bis(triethoxysilyl)tetradecane. Its structure was confirmed by NMR analysis.

후처리

  1. customThe synthesis method
  2. custom, 1993, 5, 943, and 1,14-bis(triethoxysilyl)tetradecane was synthesized
  3. customwas prepared
  4. distillationThe reaction effluent was purified by distillation

출처 및 근거

ORD 기록
ord-9449d995b31c4cc98ccd3d4b87e0e4be
출처 데이터셋
uspto-grants-2007_05
특허 번호
US07214756B2

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