Hydrazine → 4'-Hydrazino-2,2':6',2''-terpyridine

HRID 1373380

반응식

HRID 1373380 반응식
[NH2:1][NH2:2].Cl[C:4]1[CH:9]=[C:8]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][N:11]=2)[N:7]=[C:6]([C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][N:17]=2)[CH:5]=1>CC(O)CC>[N:11]1[CH:12]=[CH:13][CH:14]=[CH:15][C:10]=1[C:8]1[CH:9]=[C:4]([NH:1][NH2:2])[CH:5]=[C:6]([C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][N:17]=2)[N:7]=1

참가 물질

4

반응물 2

HCID 9321HydrazineHCID 6677484'-Chloro-2,2':6',2''-terpyridine

생성물 1

HCID 105394884'-Hydrazino-2,2':6',2''-terpyridine

시약·촉매·용매 1

HCID 6568(+-)-2-Butanol용매

실험 절차

4 ml (126 mmol) of hydrazine are added to 600 mg (2.2 mmol) of 4′-chloro-[2,2′;6′,2″]-terpyridine in 12 ml of 2-butanol. The mixture is heated at reflux for 17 hours and cooled, and [2,2′;6′,2″]terpyridin-4′-yl-hydrazine is filtered off in the form of a white solid.

후처리

  1. temperatureThe mixture is heated
  2. temperatureat reflux for 17 hours
  3. temperaturecooled
  4. filtration[2,2′;6′,2″]terpyridin-4′-yl-hydrazine is filtered off in the form of a white solid

출처 및 근거

ORD 기록
ord-8f26a72bb9c44fd3b9a732bd32cb2f68
출처 데이터셋
uspto-grants-2007_01
특허 번호
US07161005B2

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