Water → HCID 19842598, 화합물

HRID 1390176노트

반응식

HRID 1390176 반응식
[Na].[I-].[C:3]([CH2:5][CH2:6][P+:7](CCC#N)([CH2:12][CH2:13][C:14]#[N:15])[CH2:8][CH2:9][O:10][CH3:11])#[N:4].O.C(Cl)(Cl)Cl>CO>[C:3]([CH2:5][CH2:6][P:7]([CH2:12][CH2:13][C:14]#[N:15])[CH2:8][CH2:9][O:10][CH3:11])#[N:4]

참가 물질

6

반응물 4

HCID 962WaterHCID 6212ChloroformHCID 5360545SodiumHCID 20520070HCID 20520070, 화합물

생성물 1

HCID 19842598HCID 19842598, 화합물

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

1.55 g of sodium are dissolved in 100 ml of absolute methanol under an atmosphere of argon and then 26 g (0.0685 mole) of tris-(β-cyanoethyl)-2-methoxyethyl-phosphonium iodide are added to this solution. The solution is refluxed for 4 hours. After the mixture has been poured into water, extraction is performed with three 40 ml portions of chloroform. The chloroform solution is dried over magnesium sulphate, the solvent is evaporated and the oily residue distilled in a high vacuum.

후처리

  1. temperatureThe solution is refluxed for 4 hours
  2. dry with materialThe chloroform solution is dried over magnesium sulphate
  3. customthe solvent is evaporated
  4. distillationthe oily residue distilled in a high vacuum

출처 및 근거

ORD 기록
ord-3b12450557754a49a931e5938d1173c2
출처 데이터셋
uspto-grants-1979_02
특허 번호
US04138256

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