Sodium hydride → Sodium 4-chloromethyl-2, 6-di-tert-butylphenoxide

HRID 1390202

반응식

HRID 1390202 반응식
[H-].[Na+:2].[Cl:3][CH2:4][C:5]1[CH:10]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[C:8]([OH:15])=[C:7]([C:16]([CH3:19])([CH3:18])[CH3:17])[CH:6]=1>CN(C)C=O>[Cl:3][CH2:4][C:5]1[CH:10]=[C:9]([C:11]([CH3:13])([CH3:12])[CH3:14])[C:8]([O-:15])=[C:7]([C:16]([CH3:19])([CH3:18])[CH3:17])[CH:6]=1.[Na+:2]

참가 물질

4

반응물 2

HCID 24758Sodium hydrideHCID 123786012,6-Di-tert-butyl-4-(chloromethyl)phenol

생성물 1

HCID 23699397Sodium 4-chloromethyl-2, 6-di-tert-butylphenoxide

시약·촉매·용매 1

HCID 6228Dimethylformamide용매2회

실험 절차

To a stirred suspension of sodium hydride (2 g.) in dry dimethyl formamide (20 ml.) was added dropwise a solution of 4-chloromethyl-2, 6-di-tert-butylphenol (10 g.) in dimethyl formamide (40 ml.) at 25°-30° C. The mixture was stirred for 30 minutes, during which gas evolution ceased, so as to produce a solution of sodium 4-chloromethyl-2, 6-di-tert-butylphenoxide.

출처 및 근거

ORD 기록
ord-ed335a9a33ba478a905286c3c5f80dc1
출처 데이터셋
uspto-grants-1979_02
특허 번호
US04138389

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