Cyclohexanone → (1,1'-Biphenyl)-2-ol

HRID 1439625노트

반응식

HRID 1439625 반응식
S([O-])([O-])(=O)=O.[K+].[K+].[C:8]1(=[O:14])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]1>O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Cl-].[Pt+4].Cl[Pd]>[C:8]1([C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][C:8]=2[OH:14])[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1

참가 물질

5

반응물 2

HCID 7967CyclohexanoneHCID 24507Potassium Sulfate2회

생성물 1

HCID 7017(1,1'-Biphenyl)-2-ol

시약·촉매·용매 2

HCID 73357391Platinum(4+);tetrachloride;hexahydrate촉매HCID 178479784chloropalladium촉매

실험 절차

The same procedure as in Example 1 is repeated except that in place of 1g of chloroplatinic acid hexahydrate, 2.5g of potassium sulfate and at a rate of 15.5 ml/hr. of cyclohexanone dimer, 1.25g of chloropalladium, 2.0g of potassium sulfate and at a rate of 8.0 ml/hr. are employed. The conversion is found to be always 100% over the reaction period of 2,000 hours. Table 2 gives the selectivity for o-phenylphenol measured.

후처리

  1. customover the reaction period of 2,000 hours

출처 및 근거

ORD 기록
ord-958bc36869534ee69a17a532487e72c8
출처 데이터셋
uspto-grants-1977_11
특허 번호
US04060559

반응 노트

불러오는 중…