Epichlorohydrin → HCID 20135273, 화합물

HRID 1463108노트

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HRID 1463108 반응식
[CH2:1]([C:4]1[CH:5]=[C:6]([C:11]([C:14]2[CH:19]=[CH:18][C:17]([OH:20])=[C:16]([CH2:21][CH:22]=[CH2:23])[CH:15]=2)([CH3:13])[CH3:12])[CH:7]=[CH:8][C:9]=1[OH:10])[CH:2]=[CH2:3].[CH2:24]([CH:26]1[O:28][CH2:27]1)Cl.[OH-].[Na+].[CH3:31][O:32][CH2:33][CH2:34]O>>[CH2:21]([C:16]1[CH:15]=[C:14]([C:11]([C:6]2[CH:7]=[CH:8][C:9]([O:10][CH2:34][CH:33]3[O:32][CH2:31]3)=[C:4]([CH2:1][CH:2]=[CH2:3])[CH:5]=2)([CH3:13])[CH3:12])[CH:19]=[CH:18][C:17]=1[O:20][CH2:24][CH:26]1[O:28][CH2:27]1)[CH:22]=[CH2:23]

참가 물질

5

반응물 4

HCID 7835EpichlorohydrinHCID 80192-MethoxyethanolHCID 14798Sodium HydroxideHCID 74457Phenol, 4,4'-(1-methylethylidene)bis(2-(2-propen-1-yl)-

생성물 1

HCID 20135273HCID 20135273, 화합물수율 604.4%

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온도
60 °C

실험 절차

2,2-Bis(3-allyl-4-hydroxyphenyl)propane (308 g) was mixed with 2-methoxyethanol (10 g) and epichlorohydrin (740 g) and heated to 60° C. Sodium hydroxide flake (80 g) was added portionwise over 3 hours, and the mixture was stirred for a further 1/2 hour, also at 60° C. The mixture was filtered, the residue being washed with toluene, and the filtrate was evaporated to remove the solvents and the excess of epichlorohydrin. The concentrated product was filtered once more to give 334 g of 2,2-bis(3-allyl-4-(glycidyloxy)phenyl)propane, having an epoxide content of 4.03 equiv./kg and 4.5 allyl double bond equiv./kg.

후처리

  1. filtrationThe mixture was filtered
  2. washthe residue being washed with toluene
  3. customthe filtrate was evaporated
  4. customto remove the solvents
  5. filtrationThe concentrated product was filtered once more

출처 및 근거

ORD 기록
ord-f7f184fc8c6648b4b89b8457daf474b7
출처 데이터셋
uspto-grants-1984_07
특허 번호
US04463169

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