N-bromobutanimide → Methyl 5-(bromomethyl)-2-methoxybenzoate

HRID 1531917

반응식

HRID 1531917 반응식
[CH3:1][O:2][C:3](=[O:13])[C:4]1[CH:9]=[C:8]([CH3:10])[CH:7]=[CH:6][C:5]=1[O:11][CH3:12].[Br:14]N1C(=O)CCC1=O>C1C=CC=CC=1>[Br:14][CH2:10][C:8]1[CH:7]=[CH:6][C:5]([O:11][CH3:12])=[C:4]([CH:9]=1)[C:3]([O:2][CH3:1])=[O:13]

참가 물질

4

반응물 2

HCID 67184N-bromobutanimideHCID 10241396Methyl 2-methoxy-5-methylbenzoate

생성물 1

HCID 19744340Methyl 5-(bromomethyl)-2-methoxybenzoate

시약·촉매·용매 1

HCID 241Benzene용매

실험 절차

A mixture of 2-methoxy-5-methylbenzoic acid methyl ester (J.Chem.Soc.Perkin Trans.1, 1994, 1125) (1.47 g) and N-bromosuccinimide (1.45 g) in benzene (15 ml) was irradiated under a 500 W halogen lamp for 3 hours. The solvent was evaporated and the residue triturated with diethyl ether. The succinimide was filtered off and the filtrate evaporated.

후처리

  1. customThe solvent was evaporated
  2. customthe residue triturated with diethyl ether
  3. filtrationThe succinimide was filtered off
  4. customthe filtrate evaporated

출처 및 근거

ORD 기록
ord-cc5a220a1f5644198b9e4917cab8fd4f
출처 데이터셋
uspto-grants-2001_03
특허 번호
US06200981B1

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