Hydrochloric Acid → antimony (V) decanethiol

HRID 1577067

반응식

HRID 1577067 반응식
[Sb:1](=O)([O-])([O-])[O-].[Na+].[Na+].[Na+].[Sb].[CH2:10]([SH:20])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].Cl>O>[CH2:10]([SH:20])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].[Sb+5:1]

참가 물질

6

반응물 4

HCID 313Hydrochloric AcidHCID 89171-DecanethiolHCID 25469Antimonic acid, sodium saltHCID 5354495Antimony

생성물 1

HCID 86737980antimony (V) decanethiol

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
4 °C

실험 절차

Sodium antimonate obtained from U.S. Antimony Corporation (9.49 g, 0.02347 mole) was placed in a reaction vessel and 1-decanethiol from Eastman Kodak (50 ml, 0.2347 mole) added and stirred. Concentrated hydrochloric acid (3.9 ml, 0.0468 mole) was added dropwise and an immediate temperature increase of 4° C. was observed. The mixture was heated and the byproduct of the reaction, water, was distilled over at 28° C. and a vacuum of 50 mm Hg. After 2.5 hours 45.57 g of antimony (V) decanethiol was obtained. The product was filtered to remove unreacted sodium antimonate and the additional byproduct of the reaction, sodium chloride.

후처리

  1. temperatureThe mixture was heated
  2. distillationwas distilled over at 28° C.

출처 및 근거

ORD 기록
ord-c01b6090979e444dbe4c074b43123026
출처 데이터셋
uspto-grants-1981_09
특허 번호
US04287118

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