Oxygen → Trioctyl phosphate

HRID 1578833

반응식

HRID 1578833 반응식
[P:1]([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])([O:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])[O:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[O:29]=O>CCCCC(C([O-])=O)CC.CCCCC(C([O-])=O)CC.[Co+2]>[P:1]([O:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])([O:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])=[O:29]

참가 물질

4

반응물 2

HCID 977OxygenHCID 76413Octyl phosphite

생성물 1

HCID 15733Trioctyl phosphate수율 91%

시약·촉매·용매 1

HCID 8696Cobalt octoate촉매

실험 절차

A mixture of 0.2 g. of cobalt octoate and 70 g. of trioctyl phosphite is warmed in vacuo (10 mm.) at 30°C while oxygen is added over a period of six hours. The mixture is stirred throughout this period by means of a magnetic stirrer. The product is washed with an aqueous alkaline solution to remove the cobalt catalyst, having a 91% yield of trioctyl phosphate.

후처리

  1. additionA mixture of 0.2 g
  2. additionis added over a period of six hours
  3. washThe product is washed with an aqueous alkaline solution
  4. customto remove the cobalt catalyst

출처 및 근거

ORD 기록
ord-872a2dab69c84d7d96c8950da038a833
출처 데이터셋
uspto-grants-1976_02
특허 번호
US03939229

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