Hydrochloric Acid → N,N-Diethyl-P-phenylenediamine dihydrochloride

HRID 16129

반응식

HRID 16129 반응식
[CH2:1]([N:3]([CH2:11][CH3:12])[C:4]1[CH:9]=[CH:8][C:7]([NH2:10])=[CH:6][CH:5]=1)[CH3:2].[ClH:13]>C(OCC)C>[ClH:13].[ClH:13].[CH2:11]([N:3]([CH2:1][CH3:2])[C:4]1[CH:9]=[CH:8][C:7]([NH2:10])=[CH:6][CH:5]=1)[CH3:12]

참가 물질

4

반응물 2

HCID 313Hydrochloric AcidHCID 7120N,N-Diethyl-p-phenylenediamine

생성물 1

HCID 19799983N,N-Diethyl-P-phenylenediamine dihydrochloride수율 100%

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

N,N-diethyl-p-phenylenediamine (5 g, 30.4 mmol) was dissolved in diethyl ether (25 cm3) and hydrochloric acid (6 cm3, 10 M) was added and the mixture was concentrated to give the title compound (7.22 g, 100%) as a red/brown solid. dH (250 MHz; D2O): 7.68 (4H, m, ArH), 3.69 (4H, q, 7.32, NCH2), 1.11 (6H, t, 7.32, CH3); dC (62.9 MHz; D2O): 12.1 (CH3), 56.4 (NCH2), 126.8 (ArC), 127.6 (ArC), 135.5 (ArC), 139.1 (ArC).

후처리

  1. concentrationthe mixture was concentrated

출처 및 근거

ORD 기록
ord-cdcfae7f36ac4516963007566eca95a0
출처 데이터셋
uspto-grants-2010_06
특허 번호
US07737138B2

연결된 노트

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