Phenol → Sodium phenoxide

HRID 1616951

반응식

HRID 1616951 반응식
[CH2:1]([OH:13])[CH:2]=[CH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[C:14]1([OH:20])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[Na:21]>C1(C)C=CC=CC=1>[Na:21].[CH2:1]([OH:13])[CH:2]=[CH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[Na:21].[C:14]1([OH:20])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

참가 물질

6

반응물 3

HCID 996PhenolHCID 907332-Dodecen-1-olHCID 5360545Sodium

생성물 2

HCID 66602278Sodium phenoxideHCID 867166002-Dodecen-1-ol sodium salt

시약·촉매·용매 1

HCID 1140Toluene용매

반응 조건

온도
60 °C

실험 절차

Into a 5-liter flask equipped with a reflux condenser, a thermometer, and a stirrer, 3,500 mL of toluene is weighed and put, and 1141 g (6.2 mol) of 2-dodecen-1-ol and 583 g (6.2 mol) of phenol are added thereto, followed by stirring until homogeneous. 74 g (3.2 gram atom) of metallic sodium is introduced thereto at 50° C. or lower, followed by warming to 60° C. over 1 hour after the completion of the introduction, and then stirring at from 60° C. to 68° C. for 4 hours to obtain a solution of 2-dodecen-1-ol sodium salt and phenol sodium salt.

후처리

  1. customInto a 5-liter flask equipped with a reflux condenser
  2. customat 50° C.
  3. stirringstirring at from 60° C. to 68° C. for 4 hours

출처 및 근거

ORD 기록
ord-b39a2a13904b4f4491b5f63ab7b3859b
출처 데이터셋
uspto-grants-2014_07
특허 번호
US08765878B2

연결된 노트

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