Hydrochloric Acid → 2-Chloro-4,6-dinitrophenol

HRID 1638441

반응식

HRID 1638441 반응식
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[OH:13])([O-:3])=[O:2].[N+](C1C([N+]([O-])=O)=C(O)C=CC=1)([O-])=O.[ClH:27].ClCl>O>[Cl:27][C:6]1[CH:7]=[C:8]([N+:10]([O-:12])=[O:11])[CH:9]=[C:4]([N+:1]([O-:3])=[O:2])[C:5]=1[OH:13]

참가 물질

6

반응물 4

HCID 313Hydrochloric AcidHCID 14932,4-Dinitrophenol2회HCID 61912,3-Dinitrophenol2회HCID 24526Chlorine3회

생성물 1

HCID 136812-Chloro-4,6-dinitrophenol

시약·촉매·용매 1

HCID 962Water용매

실험 절차

160 parts of 2,4-dinitrophenol are suspended in 240 parts of water. Then 0.5 part of lignosulfonate (dispersant) is added to this suspension and the dinitrophenol is comminuted by ultrasonication. A reactor is charged with 210 parts of 14 % hydrochloric acid and the aqueous suspension of finely particulate 2,4-dinitrophenol and 60 parts of chlorine gas are added simultaneously at 0° C. The addition of the suspension of dinitrophenol is made over 120 minutes and the chlorine is simultaneously added over 130 minutes. When the addition of chlorine is complete, the product is isolated by filtration and washed with 250 parts of water, affording 162.4 parts of 2-chloro-4,6-dinitrophenol (corresponding to a yield of c. 83 %).

후처리

  1. additionare added simultaneously at 0° C
  2. customthe product is isolated by filtration
  3. washwashed with 250 parts of water

출처 및 근거

ORD 기록
ord-59ea38ec3eec4a408172e25edbc08f1e
출처 데이터셋
uspto-grants-1989_11
특허 번호
US04879415

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