Nitrobenzene → Azoxybenzene

HRID 1648604노트

반응식

HRID 1648604 반응식
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)([O-:3])=O.O.O.[OH-].C[N+:14]([CH3:17])(C)C>C(#N)C1C=CC=CC=1>[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)(=[N:14][C:17]1[CH:8]=[CH:9][CH:4]=[CH:5][CH:6]=1)[O-:3]

참가 물질

4

반응물 2

HCID 7416NitrobenzeneHCID 22116808Tetramethylammonium hydroxide dihydrate

생성물 1

HCID 10316Azoxybenzene수율 45%

시약·촉매·용매 1

HCID 7505Benzonitrile용매

반응 조건

온도
60 °C

실험 절차

A solution containing 10 g of nitrobenzene, 1.27 g of tetramethylammonium hydroxide dihydrate and 1 g of benzonitrile was stirred at 60° C. with nitrogen bubbled into the solution via a syringe needle for 1 hour. Analysis of a sample of the reaction product by HPLC revealed N-(4-nitrophenyl)-benzamide was produced in 45% yield and azoxybenzene was generated in 22% yield based on tetramethylammonium hydroxide.

후처리

  1. custombubbled into the solution via a syringe needle for 1 hour

출처 및 근거

ORD 기록
ord-8c37f1219c634a3799c46187d1f88a83
출처 데이터셋
uspto-grants-1995_07
특허 번호
US05436371

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