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Water → 2,4-Dichloro-6-phenoxy-1,3,5-triazine

HRID 1682080
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인쇄 미리보기

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HRID 1682080 반응식
[C:1]1([OH:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH-].[Na+].O.[N:11]1[C:18]([Cl:19])=[N:17][C:15](Cl)=[N:14][C:12]=1[Cl:13]>C1(C)C=CC=CC=1>[Cl:13][C:12]1[N:11]=[C:18]([Cl:19])[N:17]=[C:15]([O:7][C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[N:14]=1
참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 4

HCID 962WaterHCID 996PhenolHCID 7954Cyanuric chlorideHCID 14798Sodium Hydroxide

생성물 1

HCID 208072,4-Dichloro-6-phenoxy-1,3,5-triazine

시약·촉매·용매 1

HCID 1140Toluene용매

반응 조건

온도
50 °C

실험 절차

An aqueous solution of 52 parts of phenol and 50 parts by volume of a 33% aqueous solution of sodium hydroxide in 250 parts of water is treated, at a temperature of between 30° and 35° C., with a solution of 92.5 parts of cyanuric chloride in 700 parts by volume of toluene, with thorough stirring. The reaction mixture is heated to 50° C. and stirred for a further 1 hour at this temperature. The organic phase is separated off and dried with magnesium sulfate and the bulk of the toluene is distilled off. The distillation residue is filtered off with strong suction and washed with twice 20 parts by volume of toluene. After drying under reduced pressure at 30° C., 80 parts of the compound 2,4-dichloro-6-phenoxy-1,3,5-triazine melting at 111 to 116° C. are obtained.

후처리

  1. customThe organic phase is separated off
  2. dry with materialdried with magnesium sulfate
  3. distillationthe bulk of the toluene is distilled off
  4. filtrationThe distillation residue is filtered off with strong suction
  5. washwashed with twice 20 parts by volume of toluene
  6. customAfter drying under reduced pressure at 30° C.

출처 및 근거

ORD 기록
ord-7f4b82b9118c41b28bb0ee3bace198d4
출처 데이터셋
uspto-grants-1992_12
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US05175263

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