Oxygen → Aldono-1,5-lactone

HRID 1703331

반응식

HRID 1703331 반응식
[O:1]=[CH:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4].O=O>>[CH2:11]([OH:12])[CH:9]1[O:10][C:2](=[O:1])[CH:3]([OH:4])[CH:5]([OH:6])[CH:7]1[OH:8]

참가 물질

3

반응물 2

HCID 977OxygenHCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal2회

생성물 1

HCID 736Aldono-1,5-lactone

실험 절차

A process for producing hydrogen peroxide and 2-keto-D-gluconic acid, comprising, reacting D-glucose in aqueous solution with oxygen and glucose-1-oxidase to catalize oxidation of the first carbon of the D-glucose and produce D-glucono-δ-lactone, reacting the D-glucono-δ-lactone in aqueous solution with oxygen and pyranose-2-oxidase to catalyze oxidation of the second carbon of the D-glucono-δ-lactone and produce hydrogen peroxide, 2-keto-D-gluconic acid, and D-isoascorbic acid, and recovering the 2-keto-D-gluconic acid.

출처 및 근거

ORD 기록
ord-236728a4b96048628c3ac64a754d0fee
출처 데이터셋
uspto-grants-1982_09
특허 번호
US04351902

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