Hydrogen Bromide → HCID 86736145, 화합물
반응식
[I:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]([CH3:12])[CH2:9][CH2:10]O)=[CH:4][CH:3]=1.Br.NC(N)=[S:16]>O>[I:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]([CH3:12])[CH2:9][CH2:10][SH:16])=[CH:4][CH:3]=1참가 물질
5
실험 절차
70 g of 3-(p-iodophenyl) butanol was combined in solution with 138 g of hydrobromic acid (48%) and 20 g thiourea in 100 ml of water and the thiol product vacuum distilled at 126° and 0.18 mm Hg. A 41% yield of 3-(p-Iodophenyl) butane thiol was confirmed having a refractive index of n25D = 1.6071 and nmr, ir and gc readings commensurate with the structure of the desired product.
후처리
- distillationthe thiol product vacuum distilled at 126°
출처 및 근거
- ORD 기록
- ord-a570eb0d6d32463ab7ca54be87b9cf08
- 출처 데이터셋
- uspto-grants-1978_11
- 특허 번호
- US04125554
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