Chloroform → 6-(Bromomethyl)-2-naphthonitrile
반응식
[CH3:1][C:2]1[CH:3]=[C:4]2[C:9](=[CH:10][CH:11]=1)[CH:8]=[C:7]([C:12]#[N:13])[CH:6]=[CH:5]2.[Br:14]N1C(=O)CCC1=O.C(Cl)(Cl)Cl>C(Cl)(Cl)(Cl)Cl>[Br:14][CH2:1][C:2]1[CH:3]=[C:4]2[C:9](=[CH:10][CH:11]=1)[CH:8]=[C:7]([C:12]#[N:13])[CH:6]=[CH:5]2참가 물질
5
실험 절차
6.11 g of 6-methyl-2-naphthalenecarbonitrile was dissolved in 100 ml of carbon tetrachloride, and the solution was mixed with 6.63 g of N-bromosuccinimide and 30 mg of 2,2-azobis-iso-butylonitrile. After refluxing under heating for 4 hours, the resulting reaction solution was mixed with chloroform, washed with water, and then dried. By distilling off the solvent, 7.07 g of colorless 6-bromomethyl-2-naphthalenecarbonitrile was obtained.
후처리
- temperatureAfter refluxing
- temperatureunder heating for 4 hours
- customthe resulting reaction solution
- washwashed with water
- customdried
- distillationBy distilling off the solvent
출처 및 근거
- ORD 기록
- ord-7927043cb31046f0b26091015c3f9947
- 출처 데이터셋
- uspto-grants-1999_10
- 특허 번호
- US05962695
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