Potassium Hydroxide → Dipotassium D-glucarate

HRID 1751911노트

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[O:1]=[CH:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4].[OH-:13].[K+:14].[OH-:15].[Na+]>>[O:1]=[C:2]([O-:15])[C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([C:11]([O-:13])=[O:12])[OH:10])[OH:8])[OH:6])[OH:4].[K+:14].[K+:14]

참가 물질

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HCID 14797Potassium Hydroxide

HCID 14798Sodium Hydroxide

HCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

생성물 1

HCID 23624071Dipotassium D-glucarate

실험 절차

The oxidation of D-glucose was carried out as in Examples 1 and 2. However, potassium hydroxide was substituted for sodium hydroxide in the neutralization process to give crude D-glucaric acid dipotassium salt (151.25 g, 70.4% based on pure dipotassium D-glucarate). The salt was precipitated from methanol as described to give an off white solid (145.75 g, 67.9% based on pure dipotassium D-glucarate).

후처리

customto give crude D-glucaric acid dipotassium salt (151.25 g, 70.4% based on pure dipotassium D-glucarate)
customThe salt was precipitated from methanol

출처 및 근거

ORD 기록: ord-b826ddba726b4ebdb4b8ef1a35ac3762
출처 데이터셋: uspto-grants-2015_10
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09162959B2

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