2-Nitrotoluene → Azoxybenzene

HRID 1754020

반응식

HRID 1754020 반응식
C[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[N+:8]([O-:10])=O.C([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=1[N+:19]([O-])=O)C.[N+](C1C=CC=CC=1)([O-])=O>>[N+:8]([C:3]1[CH:2]=[CH:7][CH:6]=[CH:5][CH:4]=1)(=[N:19][C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:13]=1)[O-:10]

참가 물질

4

반응물 3

HCID 69442-NitrotolueneHCID 7416NitrobenzeneHCID 691561-Ethyl-2-nitrobenzene

생성물 1

HCID 10316Azoxybenzene

실험 절차

The reduction reaction was carried out in the same manner as set forth in Example 6 except for using a mixture of 1.0 mmol of o-methyl nitrobenzene and 1.0 mmol of o-ethyl nitrobenzene instead of using nitrobenzene alone, and using 19.5 mg (the amount required for swelling of the reactant in 100%) of Polymer supported reagent-2, and thereby an azoxybenzene derivative of a symmetrical structure and an azoxybenzene derivative of an asymmetrical structure were obtained as a main product, respectively.

후처리

  1. customThe reduction reaction

출처 및 근거

ORD 기록
ord-5640dc0bf2034804ae5f5c51180f0889
출처 데이터셋
uspto-grants-2015_10
특허 번호
US09169200B2

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