Azobenzene → 4-Benzeneazodiphenylamine

HRID 1781950

반응식

HRID 1781950 반응식
[N:1]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)=[N:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1>NC1C=CC=CC=1>[CH:12]1[CH:13]=[CH:14][C:9]([NH:1][C:12]2[CH:11]=[CH:10][C:9]([N:1]=[N:2][C:3]3[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=3)=[CH:14][CH:13]=2)=[CH:10][CH:11]=1

참가 물질

3

반응물 1

HCID 2272Azobenzene

생성물 1

HCID 75754-Benzeneazodiphenylamine수율 90%

시약·촉매·용매 1

HCID 6115Aniline용매

실험 절차

A solution of 25% aqueous tetramethylammonium hydroxide (8 mL) was concentrated under vacuum at 75° C. until solid material formed. Azobenzene (1.8 g) and aniline (10 mL) were added and the solution was stirred under the same conditions for 4 hours and then in the presence of air for 12 hours. Analysis of the reaction by HPLC revealed 90% yield of 4-(phenylazo)diphenylamine.

후처리

  1. concentrationA solution of 25% aqueous tetramethylammonium hydroxide (8 mL) was concentrated under vacuum at 75° C. until solid material
  2. customformed
  3. waitin the presence of air for 12 hours
  4. customAnalysis of the reaction by HPLC

출처 및 근거

ORD 기록
ord-f24cc0230cab430e999525bce7ab4a89
출처 데이터셋
uspto-grants-1997_05
특허 번호
US05633407

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