3-(3-Nitro-phenyl)-acrylonitrile → HCID 22186098, 화합물

HRID 1837516

반응식

HRID 1837516 반응식
[N+:1]([C:4]1[CH:5]=[C:6]([CH:10]=[CH:11][C:12]#[N:13])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2]>C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.[Cl-].[Rh].C1C=CC=CC=1>[N+:1]([C:4]1[CH:5]=[C:6]([CH2:10][CH2:11][C:12]#[N:13])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2]

참가 물질

4

반응물 1

HCID 556693-(3-Nitro-phenyl)-acrylonitrile

생성물 1

HCID 22186098HCID 22186098, 화합물

시약·촉매·용매 2

HCID 84599Chlorotris(triphenylphosphine)rhodium(I)촉매HCID 241Benzene용매

반응 조건

온도
40 °C

실험 절차

There are introduced into a cylinder 3 g of the product obtained in Step 1, 1.59 g of tris(triphenylphosphine)rhodium(I) chloride and 90 ml of benzene. The whole is heated for 5 hours at 40° C. under a hydrogen pressure of 5 bar. The solvent is evaporated off and the residue is purified by chromatography on silica gel using dichloromethane as eluant.

후처리

  1. customThe solvent is evaporated off
  2. customthe residue is purified by chromatography on silica gel

출처 및 근거

ORD 기록
ord-85e8aacf647b40d99e6441bc79a44ef9
출처 데이터셋
uspto-grants-2004_08
특허 번호
US06784183B2

연결된 노트

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