Ammonia → Dimorpholinodiethyl ether

HRID 1873059노트

반응식

HRID 1873059 반응식
[NH:1]1[CH2:6][CH2:5][O:4][CH2:3][CH2:2]1.[NH3:7].[CH2:8](O)[CH2:9][O:10][CH2:11][CH2:12]O>[Ni]>[O:4]1[CH2:5][CH2:6][N:1]([CH2:2][CH2:3][O:4][CH2:5][CH2:6][N:7]2[CH2:8][CH2:9][O:10][CH2:11][CH2:12]2)[CH2:2][CH2:3]1

참가 물질

5

반응물 3

HCID 222AmmoniaHCID 8083MorpholineHCID 8117Diethylene Glycol

생성물 1

HCID 80900Dimorpholinodiethyl ether수율 70%

시약·촉매·용매 1

HCID 935Nickel촉매

실험 절차

Zh. Vses. Khim. Obshchest. 14(5), 589-90 (1969) (Chem. Abstr. 72: 66879m) describes the formation of morpholine in a yield of 70% by gas-phase reaction of diethylene glycol with NH3 over a nickel catalyst in the presence of H2. Among other by-products, bis(2-morpholinoethyl) ether was isolated in a yield of from 5 to 7%.

출처 및 근거

ORD 기록
ord-3278b2f9beac4cf79bbd79851045d4a1
출처 데이터셋
uspto-grants-2000_08
특허 번호
US06111100

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