Styrene → Phenethylmethyldiethoxysilane

HRID 1873088노트

반응식

HRID 1873088 반응식
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH3:9][SiH:10]([O:14][CH2:15][CH3:16])[O:11][CH2:12][CH3:13]>[Pt].C1(C)C=CC=CC=1>[CH2:1]([CH2:9][SiH:10]([O:14][CH2:15][CH3:16])[O:11][CH2:12][CH3:13])[CH2:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

참가 물질

5

반응물 2

HCID 7501Styrene3회HCID 74848Methyldiethoxysilane2회

생성물 1

HCID 123960403Phenethylmethyldiethoxysilane수율 63%

시약·촉매·용매 2

HCID 23939Platinum촉매HCID 1140Toluene용매

반응 조건

온도
80 °C

실험 절차

Comparative Example 5. The platinum-catalyzed reaction of styrene and methyldiethoxysilane in the absence of a hydro(acyloxy)silane compound. A 212 mg sample of styrene (2 mmoles) and 279 mg of methyldiethoxysilane (HSi(CH3)(OEt)2, 2.1 mmoles) were placed in a glass reaction tube. This was followed by the addition of 0.001 mL of a toluene solution (platinum content=0.4 wt %) of a zero-valent platinum complex with divinylsiloxane. The reaction tube was subsequently sealed with Teflon™ tape, placed in an oil bath heated to 80° C., and heated for 1 hour. After cooling, analysis of the contents by gas chromatography showed an approximately 65% conversion of the vinyl group in the styrene. The hydrosilylate yield was 63% phenethylmethyldiethoxysilane. The α-phenethyl adduct: β-phenethyl adduct ratio was 1:1.65.

후처리

  1. customplaced in an oil bath
  2. temperatureheated for 1 hour
  3. temperatureAfter cooling

출처 및 근거

ORD 기록
ord-58be669e56d24e98ad49d230594d2f9b
출처 데이터셋
uspto-grants-2000_08
특허 번호
US06111126

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