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Methyl Methacrylate → HCID 169054, 화합물

HRID 1912243
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HRID 1912243 반응식
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9]([O:14][CH3:15])(=[O:13])[C:10]([CH3:12])=[CH2:11].[C:16]([O:21][CH2:22][CH:23]1[O:25][CH2:24]1)(=[O:20])[C:17]([CH3:19])=[CH2:18].N(C(C#N)(CCC)C)=NC(C#N)(CCC)C>CC(=O)CC>[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9]([O:14][CH3:15])(=[O:13])[C:10]([CH3:12])=[CH2:11].[C:16]([O:21][CH2:22][CH:23]1[O:25][CH2:24]1)(=[O:20])[C:17]([CH3:19])=[CH2:18]
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참가 물질

6

반응물 4

HCID 6658Methyl MethacrylateHCID 7501StyreneHCID 7837Glycidyl methacrylateHCID 206038Pentanenitrile, 2,2'-(1,2-diazenediyl)bis[2-methyl-

생성물 1

HCID 169054HCID 169054, 화합물

시약·촉매·용매 1

HCID 6569Methyl Ethyl Ketone용매

실험 절차

Styrene (4.8 g), methyl methacrylate (2.85 g), glycidyl methacrylate (0.3 g) and 2,2′-azobis(2-cyanopentane) (0.3 g) are dissolved in 2-butanone (40 mL) and degassed using five vacuum/nitrogen purges. The reaction is refluxed for 24 hours and then precipitated into methanol (1 L), filtered, rinsed with additional methanol and sucked dry overnight. A white polymer is obtained with Mw/Mn=16,000/8,300=1.9

후처리

  1. customdegassed
  2. temperatureThe reaction is refluxed for 24 hours
  3. customprecipitated into methanol (1 L)
  4. filtrationfiltered
  5. washrinsed with additional methanol
  6. customsucked dry overnight
  7. customA white polymer is obtained with Mw/Mn=16,000/8,300=1.9

출처 및 근거

ORD 기록
ord-3b8bf3e9ef27406f999ed71847c32f0c
출처 데이터셋
uspto-grants-2013_12
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US08609238B2

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