1-Chlorooctane → Octyltrichlorosilane

HRID 1937075

반응식

HRID 1937075 반응식
Cl[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].[Cl:10][SiH:11]([Cl:13])[Cl:12]>[Cl-].C([P+](CCCC)(CCCC)CCCC)CCC>[CH2:2]([Si:11]([Cl:13])([Cl:12])[Cl:10])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

참가 물질

4

반응물 2

HCID 81421-ChlorooctaneHCID 24811Trichlorosilane

생성물 1

HCID 21354Octyltrichlorosilane수율 85.2%

시약·촉매·용매 1

HCID 75311Tetrabutylphosphonium chloride촉매

실험 절차

In the same apparatus and procedure as Example 1 above, 0.20 g (0.68 mmol) of tetrabutylphosphonium chloride, 1.00 g (6.73 mmol) of 1-chlorooctane and 2.71 g (20.0 mmol) of trichlorosilane were reacted at 170° C. for 2 hrs. The resulting mixture was distilled to give 1.42 g of n-octyltrichlorosilane (yield; 85%).

후처리

  1. distillationThe resulting mixture was distilled

출처 및 근거

ORD 기록
ord-d8381254d70d4b2bb3357e2f5531e2a3
출처 데이터셋
uspto-grants-2002_05
특허 번호
US06392077B1

연결된 노트

불러오는 중…