Benzyl Chloride → Benzene, [(trichlorosilyl)methyl]-

HRID 1937082

반응식

HRID 1937082 반응식
[Cl-].[CH2:2]([P+](CCCC)(CCCC)CCCC)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.C(Cl)C1C=CC=CC=1.[Cl:30][SiH:31]([Cl:33])[Cl:32]>>[CH2:2]([Si:31]([Cl:33])([Cl:32])[Cl:30])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

참가 물질

4

반응물 3

HCID 7503Benzyl ChlorideHCID 24811TrichlorosilaneHCID 200231Benzyltributylphosphonium chloride

생성물 1

HCID 69863Benzene, [(trichlorosilyl)methyl]-수율 802.5%

실험 절차

In the same apparatus and procedure as Example 1 above, 0.26 g (0.79 mmol) of benzyltributylphosphonium chloride, 1.00 g (7.90 mmol) of benzyl chloride, and 3.21 g (23.7 mmol) of trichlorosilane were reacted at 150° C. for 2 hrs. The resulting mixture was distilled to give 1.43 g of benzyltrichlorosilane (yield; 80%).

후처리

  1. distillationThe resulting mixture was distilled

출처 및 근거

ORD 기록
ord-debc401b5c524fd78cb7b8c62d241c7c
출처 데이터셋
uspto-grants-2002_05
특허 번호
US06392077B1

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