Benzyl Chloride → Benzene, [(trichlorosilyl)methyl]-

HRID 1937085

반응식

HRID 1937085 반응식
[Cl-:1].[CH2:2]([P+](CCCC)(CCCC)CCCC)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH2:22](Cl)[C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1.[Cl:30][SiH2:31][Cl:32]>>[CH2:2]([SiH:31]([Cl:32])[Cl:30])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH2:22]([Si:31]([Cl:1])([Cl:32])[Cl:30])[C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1

참가 물질

5

반응물 3

HCID 7503Benzyl ChlorideHCID 61330DichlorosilaneHCID 200231Benzyltributylphosphonium chloride

생성물 2

HCID 69863Benzene, [(trichlorosilyl)methyl]-수율 53%HCID 101943102Benzyldichlorosilane수율 19%

실험 절차

In the same apparatus and procedure as Example 1 above, 0.26 g (0.79 mmol) of benyltributylphosphonium chloride, 1.01 ml (7.98 mmol) of benzyl chloride, and 2.42 g (24.0 mmol) of dichlorosilane were reacted at 150° C. for 2 hrs. The resulting mixture was distilled to give 0.29 g of benzyldichlorosilane (yield; 19%) and 0.95 g of benzyltrichlorosilane (yield; 53%).

후처리

  1. distillationThe resulting mixture was distilled

출처 및 근거

ORD 기록
ord-380bfbcecc3d4ac1a46bb07f1b202964
출처 데이터셋
uspto-grants-2002_05
특허 번호
US06392077B1

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