2,3,3,3-Tetrafluoro-2-(trifluoromethoxy)propionyl fluoride → Perfluoro(methyl vinyl ether)

HRID 1956044

반응식

HRID 1956044 반응식
[F:1][C:2]([O:10][C:11]([F:14])([F:13])[F:12])([C:6](F)([F:8])[F:7])C(F)=O.[F:15][C:16]([O:24][C:25]([F:31])([F:30])[C:26]([F:29])([F:28])[F:27])([C:20](F)([F:22])[F:21])C(F)=O>>[F:1][C:2]([O:10][C:11]([F:14])([F:13])[F:12])=[C:6]([F:8])[F:7].[F:15][C:16]([O:24][C:25]([F:30])([F:31])[C:26]([F:27])([F:28])[F:29])=[C:20]([F:22])[F:21]

참가 물질

4

반응물 2

HCID 1029052,3,3,3-Tetrafluoro-2-(trifluoromethoxy)propionyl fluorideHCID 201535112,3,3,3-Tetrafluoro-2-(perfluoroethoxy)propanoyl fluoride

생성물 2

HCID 14474Perfluoro(methyl vinyl ether)HCID 82672Perfluoroethyl vinyl ether

실험 절차

dehalocarbonylating an intermediate mixture comprising 2,3,3,3-tetrafluoro-2-(trifluoromethoxy)propionic acid fluoride (PMPF) and 2,3,3,3-tetrafluoro-2-(pentafluoroethoxy)propionic acid fluoride (PEPF) formed in step (a) to form a product mixture comprising perfluoromethyl perfluorovinyl ether (PMVE) and perfluoroethyl perfluorovinyl ether (PEVE).

출처 및 근거

ORD 기록
ord-96cecc76fb9e4f9d8eb14164a4b7e66e
출처 데이터셋
uspto-grants-1998_07
특허 번호
US05777179

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