Perfluoro(methyl vinyl ether) (HCID 14474)

개요

Perfluoro(methylvinyl ether) appears as a colorless gas. Heavier than air. Easily liquefied. Contact with the liquid may cause frost bite by evaporative cooling. May asphyxiate by displacing air. A flame may flash back from the source of ignition to the source of a leak. Under prolonged exposure to fire or heat containers may rupture violently and rocket.

이름 및 식별자

우선 이름: Perfluoro(methyl vinyl ether)
IUPAC: 1,1,2-trifluoro-2-(trifluoromethoxy)ethene
현지명: 트리플루오로메틸트리플루오로비닐에테르
영어명: Trifluoromethyl trifluorovinyl ether
분자식: C3F6O
분자량: 166.02

이름 및 동의어

Trifluoromethyl trifluorovinyl ether1187-93-5Perfluoro(methyl vinyl ether)Trifluoro(trifluoromethoxy)ethyleneEthene, 1,1,2-trifluoro-2-(trifluoromethoxy)-Ethene, trifluoro(trifluoromethoxy)-3-OXAPERFLUOROBUTENEEINECS 214-703-7UNII-6II375V3XGBRN 19074576II375V3XGETHER, TRIFLUOROMETHYL TRIFLUOROVINYL

이름 더 보기

트리플루오로메틸트리플루오로비닐에테르PMVEPerfluoro(methylvinylether)Perfluoromethylvinyl Ether (PMVE)uorovinyLtrifluoromethoxyetheneHexafluoro-3-oxa-1-buteneHexafluoro-2-oxa-3-buteneperfluorinatedmethylvinylether(Trifluoromethoxy)trifluoroethene

trifluoromethoxytrifluoroethyleneDTXSID3051599EC 214-703-7TRIFLUOROMETHYL TRIFLUORVINYL ETHERPERFLUOROVINYL PERFLUOROMETHYL ETHERRefChem:171634DTXCID10301511,1,2-trifluoro-2-(trifluoromethoxy)ethene

데이터베이스 식별자

CAS: 1187-93-5
PubChem CID: 14474
DTXSID: DTXSID3051599
UNII: 6II375V3XG
EC Number: 214-703-7
Nikkaji: J203.449B

물성

구조 계산 물성

XLogP: 2.4
극성 표면적: 9.2 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 7
회전 가능 결합 수: 1
무거운 원자 수: 10
형식 전하: 0
복잡도: 142

실험 및 물리화학적 성질

PFAS · 6건

PFAS -> Suspected persistent, mobile, toxic (PMT) PFAS or PFAS-like compounds

PFAS -> OECD Category

PFAS -> Other/unspecified

PFAS -> PFAS identified in REACH Regulation EC No. 1272/2008

SpringerMaterials PropertiesSchoenflies notation

Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR

Physical Description · 2건

Perfluoro(methylvinyl ether) appears as a colorless gas. Heavier than air. Easily liquefied. Contact with the liquid may cause frost bite by evaporative cooling. May asphyxiate by displacing air. A flame may flash back from the source of ignition to the source of a leak. Under prolonged exposure to fire or heat containers may rupture violently and rocket.

Gas Vapor

물리화학적 성질

끓는 점: -22 °C · -22 °C
밀도: 1.321 · 1.3210 (estimate)
증기압: 101.325 kPa · 101.325kPa at 20℃
수용성: 31.5 mg/L · 31.5mg/L at 28℃
InChI: InChI=1S/C3F6O/c4-1(5)2(6)10-3(7,8)9
InChIKey: BLTXWCKMNMYXEA-UHFFFAOYSA-N
SMILES: C(/F)(\F)=C(/F)\OC(F)(F)F
LogP: 1.42 · 1.42
EPA: 1 · Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)- (1187-93-5)

안전 및 규제

GHS 분류

GHS Classification · 6건

Danger

H220 (18.2%): Extremely flammable gas [Danger Flammable gases]

P203, P210, P222, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P377, P381, P403, P403+P233, P405, P410+P403, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 11 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H220: Extremely flammable gas [Danger Flammable gases]

유해성 정보

Regulatory Information · 3건

Regulation (EC) No 1935/2004 (amended)

Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 25-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13408

DOT LabelFlammable Gas

Fire Hazards · 2건

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· EXTREMELY FLAMMABLE.

Health Hazards · 2건

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.

DOT ID and Guide3153 115

Reactive GroupEthers

안전 및 보호

Fire FightingExcerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2건

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).

Nonfire Spill ResponseExcerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Isolation and Evacuation · 2건

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Immediate precautionary measure

안전 데이터

tsca: TSCA listed
rtecs: KO4350000
ridadr: UN 3153
HS 번호: 2909199090
risk_code: 20
hazard_code: F
safety_code: 23-38
위험 등급: 2.1
위험 참고 사항: Flammable gas

화학 및 산업

용도 및 제조

U.S. Production2023: 250,000 - <550,000 lb

Industry UsesMonomers

Use ClassificationPFAS (per- and polyfluoroalkyl substances) -> OECD Category

General Manufacturing Information · 2건

Plastics Material and Resin Manufacturing

Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)-: ACTIVE

응용 분야 · 1건

일반 설명A colorless gas. Heavier than air. Easily liquefied. Contact with the liquid may cause frost bite by evaporative cooling. May asphyxiate by displacing air. A flame may flash back from the source of ignition to the source of a leak. Under prolonged exposure to fire or heat containers may rupture violently and rocket.