Diphenyl Ether → 1-Propanone, 1,1'-(oxydi-4,1-phenylene)bis-

HRID 1979970노트

반응식

HRID 1979970 반응식
[C:1]1([O:7][C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:14](Cl)(=[O:17])[CH2:15][CH3:16].[Cl-].[Al+3].[Cl-].[Cl-]>C(=S)=S>[C:14]([C:11]1[CH:10]=[CH:9][C:8]([O:7][C:1]2[CH:2]=[CH:3][C:4]([C:1](=[O:7])[CH2:2][CH3:3])=[CH:5][CH:6]=2)=[CH:13][CH:12]=1)(=[O:17])[CH2:15][CH3:16]

참가 물질

5

반응물 3

HCID 7583Diphenyl EtherHCID 62324Propionyl chlorideHCID 6451240Aluminum(III) Chloride

생성물 1

HCID 106842951-Propanone, 1,1'-(oxydi-4,1-phenylene)bis-

시약·촉매·용매 1

HCID 6348Carbon Disulfide용매

실험 절차

Diphenyl ether (67 grams) was mixed with about 79 grams of propionyl chloride and 109 grams of aluminum chloride in about 150 ml of carbon disulfide. The product, 4-propionylphenyl ether, was isolated by hydrolysis of the mixture and conventional recrystallization techniques.

출처 및 근거

ORD 기록
ord-306e3264f3054b1194b6e8b12b767234
출처 데이터셋
uspto-grants-1984_11
특허 번호
US04483984

반응 노트

불러오는 중…