Water → Oxirane, 2-((4-chlorophenyl)methyl)-

HRID 2107064

반응식

HRID 2107064 반응식
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH2:8][CH:9]=[CH2:10])=[CH:4][CH:3]=1.ClC1C=CC=C(C(OO)=[O:19])C=1.O>C(Cl)(Cl)Cl>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH2:8][CH:9]2[O:19][CH2:10]2)=[CH:4][CH:3]=1

참가 물질

5

반응물 3

HCID 962WaterHCID 70297m-Chloroperbenzoic acidHCID 110190641-Allyl-4-chlorobenzene

생성물 1

HCID 148012Oxirane, 2-((4-chlorophenyl)methyl)-

시약·촉매·용매 1

HCID 6212Chloroform용매

실험 절차

To a solution of 3-(4-chlorophenyl)prop-1-ene (9.0 g) in chloroform (100 ml) was added portionwise metachloroperbenzoic acid (12.2 g), and the solution was stirred for 5 h at room temperature. The mixture was poured into water, the water layer was separated and the organic layer washed successively with sodium bicaronate, sodium sulphite and water. After drying, evaporation of the solvent gave 1-(4-chlorophenyl)-2,3-epoxypropane as a pale yellow oil. (9.51 g). NMR in CDCl3 :

후처리

  1. customthe water layer was separated
  2. washthe organic layer washed successively with sodium bicaronate, sodium sulphite and water
  3. customAfter drying
  4. customevaporation of the solvent

출처 및 근거

ORD 기록
ord-b212209cb977459caa6ffe79f2a61af2
출처 데이터셋
uspto-grants-1990_06
특허 번호
US04933357

연결된 노트

불러오는 중…