3-Phenylprop-2-Enal → HCID 54566724, 화합물

HRID 2107820노트

반응식

HRID 2107820 반응식
[CH:1](=O)[CH:2]=[CH:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[CH2:11]1[CH2:16][CH:15]=[C:14]([CH2:17][C:18]#[N:19])[CH2:13][CH2:12]1.[OH-].[Na+]>C(O)C>[C:14]1([C:17](=[CH:1][CH:2]=[CH:3][C:4]2[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=2)[C:18]#[N:19])[CH2:13][CH2:12][CH2:11][CH2:16][CH:15]=1

참가 물질

5

반응물 3

HCID 3073-Phenylprop-2-EnalHCID 14798Sodium HydroxideHCID 814611-Cyclohexene-1-acetonitrile

생성물 1

HCID 54566724HCID 54566724, 화합물

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

In a 50 ml 3-necked round bottom flask equipped with a nitrogen inlet, condensor and magnetic stir bar is placed cinnamaldehyde (2.64 g, 0.02 mol), 1-cyclohexenylacetonitrile (2.42 g, 0.02 mol) and sodium hydroxide (0.2 g, 0.005 mol) in absolute ethanol (25 ml). The reaction is stirred at room temperature until completion, during which time the crude product precipitates from solution. The precipitate is filtered, washed with water and dried. Recrystallization from ethanol yields a yellowish solid with maximum absorption at 338 nm and extinction coefficient of 45,825.

후처리

  1. customIn a 50 ml 3-necked round bottom flask equipped with a nitrogen inlet
  2. customprecipitates from solution
  3. filtrationThe precipitate is filtered
  4. washwashed with water
  5. customdried
  6. customRecrystallization from ethanol
  7. customyields a yellowish solid
  8. customwith maximum absorption at 338 nm and extinction coefficient of 45,825

출처 및 근거

ORD 기록
ord-46eec831cee04862a60a82141c1d74ac
출처 데이터셋
uspto-grants-1990_06
특허 번호
US04935533

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