Hydrogen Peroxide → 1,2-Epoxycyclooctane

HRID 2166855

반응식

HRID 2166855 반응식
OO.Cl[CH2:4][C:5]([C:7](Cl)(Cl)Cl)=[O:6].[CH:11]1[CH2:18][CH2:17]CCC[CH2:13][CH:12]=1.C(Cl)(Cl)Cl>O>[CH:4]12[O:6][CH:5]1[CH2:7][CH2:13][CH2:12][CH2:11][CH2:18][CH2:17]2

참가 물질

6

반응물 4

HCID 784Hydrogen PeroxideHCID 6212ChloroformHCID 136091-CycloocteneHCID 281882-Propanone, 1,1,1,3-tetrachloro-

생성물 1

HCID 675131,2-Epoxycyclooctane수율 83%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

There were added 13.68 parts of a 50% aqueous hydrogen peroxide to a refluxing mixture of 3.92 parts of tetrachloroacetone, 11.58 parts of cyclooctene and 149 parts of chloroform. Water was removed continuously as it was formed, over a period of 4 hours of heating. The removed water was then added to the reaction mixture. The organic phase was then separated from the aqueous phase. Based on VPC analysis is there was obtained an 83% yield of cyclooctene oxide.

후처리

  1. customWater was removed continuously as it
  2. customwas formed, over a period of 4 hours
  3. temperatureof heating
  4. customThe organic phase was then separated from the aqueous phase

출처 및 근거

ORD 기록
ord-4325ce9dd96c484c9bfa7f553a421349
출처 데이터셋
uspto-grants-1983_06
특허 번호
US04389529

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