Oxygen → 1,3-Adamantanediol

HRID 2185620

반응식

HRID 2185620 반응식
C12CC3CC(CC(C3)C1)C2.FC(F)(F)C1C=CC2N=NN([OH:21])C=2C=1.O=O.[C:27]12([OH:37])[CH2:36][CH:31]3[CH2:32][CH:33]([CH2:35][CH:29]([CH2:30]3)[CH2:28]1)[CH2:34]2>C(O)(=O)C>[C:29]12([OH:21])[CH2:30][CH:31]3[CH2:32][CH:33]([CH2:34][C:27]([OH:37])([CH2:36]3)[CH2:28]1)[CH2:35]2

참가 물질

6

반응물 4

HCID 977OxygenHCID 9238AdamantaneHCID 641521-AdamantanolHCID 6881941-Hydroxy-6-(trifluoromethyl)benzotriazole

생성물 1

HCID 5738291,3-Adamantanediol

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

A mixture of 10 mmol of adamantane, 0.8 mmol of 6-trifluoromethyl-1-hydroxybenzotriazole, 0.06 mmol of acetylacetonatocobalt(III), and 25 ml of acetic acid was stirred at 90° C. in an oxygen atmosphere (1 atm) for 8 hours. A gas chromatographic analysis of products in a reaction mixture found that 1-adamantanol and 1,3-adamantanediol were formed in yields of 38% and 4%, respectively, with a conversion rate from adamantane of 48%.

출처 및 근거

ORD 기록
ord-c57151d71df74416857985f15f37c92a
출처 데이터셋
uspto-grants-2002_06
특허 번호
US06403521B1

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