Triethyl phosphite → Diethyl (3,3-diphenylallyl)phosphonate

HRID 2287294

반응식

HRID 2287294 반응식
[C:1]1([C:7]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[CH:8][CH2:9]Cl)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[P:17]([O:24]CC)([O:21][CH2:22][CH3:23])[O:18][CH2:19][CH3:20]>>[C:1]1([C:7]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[CH:8][CH2:9][P:17](=[O:24])([O:21][CH2:22][CH3:23])[O:18][CH2:19][CH3:20])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

참가 물질

3

반응물 2

HCID 31215Triethyl phosphiteHCID 128901653-Chloro-1,1-diphenylpropene2회

생성물 1

HCID 13328742Diethyl (3,3-diphenylallyl)phosphonate수율 108.2%

실험 절차

A mixture of 40.8 g (0.155 mol) of 3,3-diphenylallyl chloride (11a) and 94.48 g (0.569 mol) of triethyl phosphite was stirred with refluxing for 24 hours. The disappearance of the 3,3-diphenylallyl chloride (11a) was ascertained, before the reaction was terminated. After cooling, the reaction mixture was distilled with a Claisen flask equipped with a vigreux to obtain 55.39 g of the target compound.

후처리

  1. temperaturewith refluxing for 24 hours
  2. customwas terminated
  3. temperatureAfter cooling
  4. distillationthe reaction mixture was distilled with a Claisen flask
  5. customequipped with a vigreux

출처 및 근거

ORD 기록
ord-d7ec43e8937e4924a5069c81784bbde9
출처 데이터셋
uspto-grants-2000_07
특허 번호
US06083651

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