Benzoyl Peroxide → (2,4-Dichloro-5-nitrophenyl)methyl bromide

HRID 231411

반응식

HRID 231411 반응식
[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[C:5]([N+:9]([O-:11])=[O:10])=[CH:4][C:3]=1[CH3:12].[Br:13]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[C:5]([N+:9]([O-:11])=[O:10])=[CH:4][C:3]=1[CH2:12][Br:13]

참가 물질

5

반응물 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 2516791,5-Dichloro-2-methyl-4-nitrobenzene

생성물 1

HCID 14501785(2,4-Dichloro-5-nitrophenyl)methyl bromide

시약·촉매·용매 1

HCID 5943Carbon Tetrachloride용매

실험 절차

This compound was prepared in a manner similar to Example 1 Step F using 2,4-dichloro-5-nitrotoluene (62.0 g, 0.3 mole), N-bromosuccinimide (160.2 g, 0.9 mole), benzoyl peroxide (2.0 g) and carbon tetrachloride (500 ml) to yield (2,4-dichloro-5-nitrophenyl)methyl bromide. The NMR spectrum was consistent with the proposed structure.

후처리

  1. customThis compound was prepared in a manner similar to Example 1 Step F

출처 및 근거

ORD 기록
ord-b2fd7d6809ae443fa2e3d2bbc9fa27eb
출처 데이터셋
uspto-grants-1989_07
특허 번호
US04846875

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