Hydrochloric Acid → HCID 15702746, 화합물

HRID 232260

반응식

HRID 232260 반응식
[C:1]1(=[O:8])[CH2:7][CH2:6][CH2:5][CH2:4][CH:3]=[CH:2]1.[C-:9]#[N:10].C([Al+]CC)C.Cl>C1(C)C=CC=CC=1>[O:8]=[C:1]1[CH2:7][CH2:6][CH2:5][CH2:4][CH:3]([C:9]#[N:10])[CH2:2]1

참가 물질

5

반응물 3

HCID 313Hydrochloric AcidHCID 707232-Cyclohepten-1-oneHCID 16686413Diethyl aluminum cyanide

생성물 1

HCID 15702746HCID 15702746, 화합물

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

To 100 mL of toluene add 2-cyclohepten-1-one (11.0 g, 0.1 mol) and 200 mL (1M solution in toluene, 0.2 mol) of diethylaluminum cyanide. Monitor the reaction by thin-layer chromatography. Upon completion add 1M aqueous HCl until gas evolution ceases. Extract twice with 100 mL of ether. Dry the organic phase with Na2SO4. Filter off the drying agent and evaporate the solvent in vacuo to obtain the title compound.

후처리

  1. customMonitor the reaction by thin-layer chromatography
  2. extractionExtract twice with 100 mL of ether
  3. dry with materialDry the organic phase with Na2SO4
  4. filtrationFilter off the drying agent
  5. customevaporate the solvent in vacuo

출처 및 근거

ORD 기록
ord-e95315393a654245bf2d5423cbf03910
출처 데이터셋
uspto-grants-1989_07
특허 번호
US04851526

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