(+-)-2-Butanol → (1-Methylpropoxycarbonyl)sulfenyl chloride

HRID 232725

반응식

HRID 232725 반응식
Cl[C:2]([S:4][Cl:5])=[O:3].[CH3:6][CH:7]([OH:10])[CH2:8][CH3:9]>>[CH3:6][CH:7]([O:10][C:2]([S:4][Cl:5])=[O:3])[CH2:8][CH3:9]

참가 물질

3

반응물 2

HCID 6568(+-)-2-ButanolHCID 75990(Chlorothio)formyl chloride

생성물 1

HCID 13633290(1-Methylpropoxycarbonyl)sulfenyl chloride수율 39.1%

실험 절차

Chlorocarbonylsulfenyl chloride (13.1 g, 0.1 mol) was mixed with 2-butanol (6.7 g, 0.09 mol)and warmed to about 35° to 40° C. for one hour. Distillation resulted in the tithe compound (5.93 g) Bp. 70° C./0.8 mm Hg. NMR spectrum was consistent with the structure.

후처리

  1. temperaturewarmed to about 35° to 40° C. for one hour
  2. distillationDistillation

출처 및 근거

ORD 기록
ord-61cd90b086e14eeaa59c139b8c8dc5ed
출처 데이터셋
uspto-grants-1997_01
특허 번호
US05591764

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