Ethyl chloroacetate → Acetic acid, 2-phenoxy-, ethyl ester

HRID 235985

반응식

HRID 235985 반응식
[C:1](=O)([O:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)OC.ClC[C:14]([O:16][CH2:17][CH3:18])=[O:15].CC1C(CN2CCC(N3CCC(N4C(=O)NC5C4=CC=CC=5)CC3)CC2)=CC=CC=1>>[O:4]([CH2:1][C:14]([O:16][CH2:17][CH3:18])=[O:15])[C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][CH:10]=1

참가 물질

4

반응물 3

HCID 7751Ethyl chloroacetateHCID 139482Carbonic acid, methyl phenyl esterHCID 10092649Tbpb

생성물 1

HCID 17365Acetic acid, 2-phenoxy-, ethyl ester수율 96%

반응 조건

온도
120 °C

실험 절차

A mixture of 3.8 g of methyl phenyl carbonate, 3.06 g of ethyl chloroacetate, and 0.42 g of TBPB was heated at 120° C. for 2 hours. Distillation of the resulting reaction mixture provided a 96 percent yield of ethyl phenoxyacetate.

후처리

  1. distillationDistillation of the resulting reaction mixture

출처 및 근거

ORD 기록
ord-84617750b2de451891c31139817feac1
출처 데이터셋
uspto-grants-1987_02
특허 번호
US04642349

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