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llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
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Isopropanol → n-(2-Hydroxyethyl)ammonium methyl sulfate

HRID 23865
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HRID 23865 반응식
[N:1](CCO)(CCO)[CH2:2][CH2:3][OH:4].C(O)(C)C.[S:15]([O:20]C)([O:18][CH3:19])(=[O:17])=[O:16]>C(O)CC>[CH3:19][O:18][S:15]([O-:20])(=[O:17])=[O:16].[OH:4][CH2:3][CH2:2][NH3+:1]
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참가 물질

5

반응물 3

HCID 3776IsopropanolHCID 6497Dimethyl SulfateHCID 7618Triethanolamine

생성물 1

HCID 22035489n-(2-Hydroxyethyl)ammonium methyl sulfate

시약·촉매·용매 1

HCID 10311-Propanol용매

실험 절차

Triethanol amine (149 g) and 547 g of hydrogenated tallow fatty acid were used and subjected to an esterification reaction at 200° C. under nitrogen atmosphere for 10 hours, and to this was added 139 g of isopropanol, and this was subjected to a quaternizing reaction at 60° C. by using 126 g of dimethyl sulfate to obtain a propanol solution of N-methyl-N,N-bis(hydrogenated tallow alkanoyl oxyethyl)-N-(2-hydroxyethyl)ammonium methyl sulfate. It was found through NMR measurements that this solution had a long-chain alkyl quaternary ammonium salt content of 12%, a di-long-chain alkyl quaternary ammonium salt content of 35% and mono-long-chain alkyl quaternary ammonium salt content of 15%. The resulting isopropanol solution was taken in a manner so as to set the total amount of quaternary ammonium salt to 5 g, and this was mixed with 2 g of ethyleneoxide 12 mole adduct (HLB=14.0) of hydrogenated tallow fatty acid methyl ester, in the same manner as Example 1 to prepare 100 g of softener composition.

후처리

  1. customsubjected to an esterification reaction at 200° C. under nitrogen atmosphere for 10 hours
  2. customthis was subjected to a quaternizing reaction at 60° C.

출처 및 근거

ORD 기록
ord-da1ff4e09f8e4a52ba3403d8ddb3a3e3
출처 데이터셋
uspto-grants-2005_02
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US06855682B2

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