Benzylamine → N-(1,1-Dimethoxypropan-2-ylidene)-1-phenylmethanamine

HRID 239125

반응식

HRID 239125 반응식
[CH3:1][O:2][CH:3]([O:7][CH3:8])[C:4]([CH3:6])=O.S([O-])([O-])(=O)=O.[Mg+2].[CH2:15]([NH2:22])[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1>>[CH2:15]([N:22]=[C:4]([CH3:6])[CH:3]([O:7][CH3:8])[O:2][CH3:1])[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1

참가 물질

4

반응물 3

HCID 7504BenzylamineHCID 24083Sulfuric acid magnesium salt (1:1)HCID 80650Pyruvic aldehyde dimethyl acetal

생성물 1

HCID 71380533N-(1,1-Dimethoxypropan-2-ylidene)-1-phenylmethanamine

실험 절차

12.9 mL 1,1-dimethoxyacetone was added to 10 mL benzylamine in 100 mL petrolether. Magnesiumsulfate was added and the reaction was stirred over night at RT. The mixture was filtered and evaporated to give 18.9 g of the desired product. (M+H)+: 209

후처리

  1. filtrationThe mixture was filtered
  2. customevaporated

출처 및 근거

ORD 기록
ord-b3bc05dd952240c8a50ff875b993000c
출처 데이터셋
uspto-grants-2014_02
특허 번호
US08642774B2

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