Monochloramine → 4-(2-Chloro-ethyl)-2,6-dimethyl-morpholine hydrochloride

반응식

[CH3:1][CH:2]1[O:7][CH:6]([CH3:8])[CH2:5][N:4]([CH2:9][CH:10](O)C)[CH2:3]1.[Cl:13]N>>[ClH:13].[Cl:13][CH2:10][CH2:9][N:4]1[CH2:3][CH:2]([CH3:1])[O:7][CH:6]([CH3:8])[CH2:5]1

참가 물질

반응물 2

HCID 25423Monochloramine

HCID 98999alpha,2,6-Trimethylmorpholin-4-ylethanol

생성물 1

HCID 129555394-(2-Chloro-ethyl)-2,6-dimethyl-morpholine hydrochloride

실험 절차

An amount, 389.3 grams, of 2,6-dimethyl-N-(2-hydroxypropyl) morpholine (2.25 moles) was condensed with the free chloroamine obtained from 481.5 grams N-chloroethyl-2,6-dimethylmorpholine hydrochloride (2.25 moles) as described above to give 415.9 grams (58.8%) of the catalyst, bp 127°-129° C. at 0.3 mm of Hg. The structure was confirmed as that of the title compound by elemental analysis, calc. 64.9 C, 10.9 H, 8.9 N; found 64.4 C, 10.6 H, 8.9 N.

출처 및 근거

ORD 기록: ord-2bf37e33554e4fd9b07d5dfa61613237
출처 데이터셋: uspto-grants-1987_11
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04705840

반응 노트

불러오는 중…